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Chloramines and Disinfection By-Products: Occurrence and Control

A technical paper by Olympian Water Testing specialists

Table of Contents

The history and development of chloramine use as a disinfectant in water treatment











[1] American Water Works Association. (2019). Chloramines in Drinking Water.
[2] United States Environmental Protection Agency. (2010). Disinfection with Chloramines.
[3] United States Environmental Protection Agency. (2017). Disinfection Byproducts Rule.
[4] National Sanitation Foundation International. (2019). Chloramines in Drinking Water.

The benefits and drawbacks of using chloramines compared to other disinfectants such as chlorine

Chloramines in Drinking Water (6)









[1] S. R. Edzwald, "Chlorine and chloramines as water disinfectants," Journal – American Water Works Association, vol. 94, no. 8, pp. 102-112, 2002.
[2] S. R. Edzwald, "Chlorination and chloramination," in Water Quality and Treatment: A Handbook on Drinking Water, 6th ed, McGraw-Hill, 2011, pp. 8-1 to 8-22.
[3] R. W. Herricks, "Chloramines in Drinking Water," Journal – American Water Works Association, vol. 92, no. 12, pp. 64-74, 2000.
[4] M. W. LeChevallier and K. E. McFeters, "Microbiological aspects of chloramination," Journal – American Water Works Association, vol. 84, no. 7, pp. 88-96, 1992.
[5] R. W. Herricks, "Chlorination and chloramination," in Water Quality and Treatment: A Handbook on Drinking Water, 6th ed, McGraw-Hill, 2011, pp. 8-1 to 8-22.

The formation and occurrence of disinfection by-products (DBPs) in chloraminated water systems

cleaning chemicals (2)









[1] K. M. Reckhow, “Disinfection by-products in drinking water: formation, analysis, and control,” Journal of Environmental Engineering, vol. 117, no. 2, pp. 111–124, 1991.
[2] A. L. Leaf, “The chemistry of nitrosamines in drinking water,” Environmental Science & Technology, vol. 31, no. 3, pp. 538–543, 1997.
[3] K. M. Reckhow, “Halonitromethanes in drinking water,” Journal of Environmental Engineering, vol. 121, no. 1, pp. 68–75, 1995.
[4] J. R. Bucher, “Cancer in laboratory animals following exposure to nitrosamines,” Environmental Health Perspectives, vol. 53, pp. 3–22, 1983.
[5] J. R. Huff, “Epidemiological evidence on the human health effects of exposure to disinfection by-products in drinking water,” Journal of Environmental Science and Health, Part C: Environmental Carcinogenesis & Ecotoxicology Reviews, vol. 21, no. 1, pp. 1–41, 2003.
[6] K. M. Reckhow, “Control of disinfection by-products in drinking water,” Journal of Environmental Engineering, vol. 117, no. 2, pp. 125–138, 1991.
[7] K. M. Reckhow and C. M. Lee, “Control of nitrosamines in drinking water,” Journal of Environmental Engineering, vol. 119, no. 3, pp. 515–529, 1993.
[8] K. M. Reckhow and C. M. Lee, “Control of halonitromethanes in drinking water,” Journal of Environmental Engineering, vol. 121, no. 1, pp. 76–84, 1995.

The health effects of DBPs on humans and animals

young woman doctor with old woman patient











[1] Environmental Protection Agency. (2017). Disinfection Byproducts.
[2] National Toxicology Program. (2010). Report on Carcinogens.
[3] California Environmental Protection Agency. (2005). Public Health Goal for Trihalomethanes in Drinking Water.
[4] Environmental Protection Agency. (2017). Disinfection Byproducts.
[5] National Toxicology Program. (2010). Report on Carcinogens.
[6] Environmental Protection Agency. (2017). Disinfection Byproducts.
[7] California Environmental Protection Agency. (2005). Public Health Goal for Trihalomethanes in Drinking Water. Retrieved from https://www.waterboards.ca.gov/

Techniques for controlling and reducing the formation of DBPs in chloraminated water systems

Chloramines in Drinking Water (7)









[1] J. M. Symons, "Removal of precursors for disinfection by-product formation," Journal – American Water Works Association, vol. 88, no. 6, pp. 78-88, 1996.
[2] E. R. Blatchley III and J. R. Suydam, "Effect of pH on the formation of halogenated disinfection by-products," Environmental Science & Technology, vol. 38, no. 11, pp. 3701-3707, 2004.
[3] G. A. McFeters, "Evaluation of chlorine dioxide and hydrogen peroxide as alternatives to chlorine for control of disinfection by-products," Applied and Environmental Microbiology, vol. 61, no. 1, pp. 25-30, 1995.
[4] A. R. von Gunten, "Oxidants and ozone in drinking water treatment," Water Research, vol. 38, no. 20, pp. 4366-4379, 2004.
[5] R. L. Jolley, "Disinfection by-products: regulations and health effects," Journal – American Water Works Association, vol. 94, no. 9, pp. 72-82, 2002.
[6] G. A. McFeters, "Evaluation of chlorine dioxide and hydrogen peroxide as alternatives to chlorine for control of disinfection by-products," Applied and Environmental Microbiology, vol. 61, no. 1, pp. 25-30, 1995.

The impact of source water quality on DBP formation

Chloramines in Drinking Water (2)

The quality of the source water used in a water treatment system plays a significant role in the formation of disinfection by-products (DBPs). This subtopic will examine how the characteristics of the source water, such as pH, temperature, and the presence of natural organic matter, can influence the formation of DBPs.

One of the key factors that can impact the formation of DBPs is the pH of the source water. High pH levels can promote the formation of certain DBPs, such as haloacetic acids (HAAs), while low pH levels can inhibit the formation of certain DBPs, such as nitrosamines. [1] Therefore, controlling the pH of the source water can be an effective strategy for minimizing the formation of DBPs.

The presence of natural organic matter (NOM) in the source water can also significantly impact the formation of DBPs. NOM can act as a precursor for the formation of certain DBPs, such as HAAs and trihalomethanes (THMs). [2] Therefore, reducing the amount of NOM in the source water can help to minimize the formation of DBPs.

Temperature is another factor that can impact the formation of DBPs. High temperatures can increase the formation of certain DBPs, such as THMs, while lower temperatures can inhibit the formation of certain DBPs, such as HAAs. [3] Therefore, controlling the temperature of the source water can also be an effective strategy for minimizing the formation of DBPs.

In conclusion, the quality of the source water used in a water treatment system plays a significant role in the formation of DBPs. The pH, temperature, and the presence of natural organic matter can all impact the formation of DBPs. Therefore, controlling these factors can be an effective strategy for minimizing the formation of DBPs. Additionally, regular monitoring and testing of source water quality is crucial in order to effectively manage and control the formation of DBPs. Furthermore, it is important for water treatment facilities to stay up-to-date with the latest research and technology in order to implement the most effective techniques for controlling the source water quality and minimize the formation of DBPs.

[1] S. A. Snyder and R. E. Hoehn, “Impact of pH on the Formation of Disinfection By-Products,” Journal of the American Water Works Association, vol. 96, no. 1, pp. 80-89, Jan. 2004.
[2] M. L. Brusseau, “Natural Organic Matter and Disinfection By-Products: A Primer,” Journal of the American Water Works Association, vol. 96, no. 1, pp. 90-98, Jan. 2004.
[3] S. A. Snyder and R. E. Hoehn, “Impact of Temperature on the Formation of Disinfection By-Products,” Journal of the American Water Works Association, vol. 96, no. 1, pp. 99-106, Jan. 2004.

The role of chlorine and chloramines in controlling the spread of waterborne pathogens

pink bacteria 23

Chlorine and chloramines are widely used as disinfectants in water treatment systems to control the spread of waterborne pathogens. This subtopic will explore how chlorine and chloramines are used to prevent the spread of harmful bacteria, viruses, and other pathogens in water systems.

Chlorine is a powerful oxidizing agent that has been used for over a century to disinfect water. When chlorine is added to water, it reacts with the pathogens present, killing or inactivating them [1]. Chlorine is effective against a wide range of pathogens, including bacteria, viruses, and protozoa [2]. Additionally, chlorine can also help to control the growth of biofilms, which can harbor pathogens, in water systems [3].

Chloramines, which are a mixture of chlorine and ammonia, are also commonly used as a disinfectant in water treatment systems. Like chlorine, chloramines react with pathogens in the water, killing or inactivating them. [4] Chloramines are particularly effective against bacteria, such as Escherichia coli and Legionella pneumophila [5]. Additionally, chloramines have a longer residual effect in water than chlorine, which means that they continue to disinfect the water for a longer period of time [6].

While chlorine and chloramines are effective in controlling the spread of waterborne pathogens, they can also form disinfection by-products (DBPs) when they react with organic and inorganic matter present in the water. Therefore, it is important to carefully monitor and control the levels of chlorine and chloramines in water systems in order to minimize the formation of DBPs while still effectively controlling the spread of pathogens.

In conclusion, chlorine and chloramines are effective tools for controlling the spread of waterborne pathogens in water systems. Chlorine is a powerful oxidizing agent that is effective against a wide range of pathogens, while chloramines are particularly effective against bacteria and have a longer residual effect in water. However, it is important to carefully monitor and control the levels of chlorine and chloramines in water systems in order to minimize the formation of DBPs while still effectively controlling the spread of pathogens. Regular monitoring and testing of chlorine and chloramine levels, as well as source water quality, can help to ensure that the disinfection process is both effective and safe. Additionally, water treatment facilities should stay up-to-date with the latest research and technology in order to implement the most effective techniques for controlling waterborne pathogens while minimizing the formation of DBPs.

[1] Centers for Disease Control and Prevention. (2017). Chlorination of Drinking Water.
[2] World Health Organization. (2011). Guidelines for Drinking-water Quality.
[3] American Water Works Association. (2013). Chlorine and Chloramines.
[4] Environmental Protection Agency. (2019). Chloramines in Drinking Water.
[5] American Water Works Association Research Foundation. (2010). Control of Legionella in Drinking Water Systems.
[6] United States Geological Survey. (2016). Chloramines in Water Treatment. Retrieved from https://www.usgs.gov/

The impact of water treatment on the distribution system and the effectiveness of disinfection

water treatment (10)

Water treatment is essential to ensure the safety and quality of drinking water, but it can also impact the distribution system and the effectiveness of disinfection. This subtopic will investigate how the treatment of water can affect the distribution system and the effectiveness of disinfection.

One major impact of water treatment on the distribution system is the formation of disinfection by-products (DBPs). When disinfectants, such as chlorine and chloramines, react with organic and inorganic matter present in the water, DBPs can be formed. These DBPs can accumulate in the distribution system, potentially leading to higher levels of DBPs in the water delivered to consumers. [1] Therefore, it is important to carefully monitor and control the levels of disinfectants in the water to minimize the formation of DBPs in the distribution system.

Another impact of water treatment on the distribution system is the potential for corrosion of pipes and other infrastructure. Chlorine and chloramines can react with the materials used in the distribution system, leading to corrosion and potential leaks. [2] Therefore, it is important to carefully monitor the levels of disinfectants in the water and to use corrosion inhibitors to protect the distribution system.

The effectiveness of disinfection can also be impacted by water treatment. The presence of certain minerals and other contaminants in the water can reduce the effectiveness of disinfectants [3]. Additionally, the formation of DBPs can also reduce the effectiveness of disinfectants by consuming the disinfectant before it can react with pathogens in the water [4]. Therefore, it is important to carefully monitor and control the levels of disinfectants and other contaminants in the water to ensure effective disinfection.

In conclusion, water treatment is essential to ensure the safety and quality of drinking water, but it can also impact the distribution system and the effectiveness of disinfection. The formation of DBPs and potential corrosion of pipes can be major impacts on the distribution system. Additionally, the presence of certain minerals and other contaminants, as well as the formation of DBPs, can reduce the effectiveness of disinfectants in the water. Therefore, it is important to carefully monitor and control the levels of disinfectants and other contaminants in the water to ensure effective disinfection and protect the distribution system. Regular testing and monitoring of the waterin the distribution system is crucial in order to identify and address any issues that may arise. Furthermore, it is important for water treatment facilities to stay up-to-date with the latest research and technology in order to implement the most effective techniques for controlling and reducing the formation of DBPs while ensuring the safety and quality of treated water for consumers.

[1] R.L. Jolley, “Disinfection By-products: Occurrence, Formation, Health Effects, and Control,” Journal of Environmental Science and Health, vol. 42, no. 8, pp. 1449-1473, 2007.
[2] R.L. Jolley, “Chlorine and Chloramines as Disinfectants,” Journal of Environmental Science and Health, vol. 42, no. 8, pp. 1409-1423, 2007.
[3] J.S. Sabatini, “The Impact of Water Quality on Disinfection Effectiveness,” Journal of Environmental Science and Health, vol. 42, no. 8, pp. 1435-1448, 2007.
[4] J.S. Sabatini, “Disinfection By-products: Occurrence, Formation, Health Effects, and Control,” Journal of Environmental Science and Health, vol. 42, no. 8, pp. 1474-1491, 2007.

The economic costs of chloramines and DBP formation

Chloramines in Drinking Water

The use of chloramines as a disinfectant in water treatment systems can come with significant economic costs. This subtopic will examine the costs of using chloramines, including the costs of equipment, chemicals, and labor, as well as the costs associated with controlling disinfection by-product (DBP) formation.

One of the major costs associated with using chloramines is the cost of equipment. The use of chloramines requires specialized equipment, such as chloramine feed systems and chloramine analyzers, which can be costly to purchase and maintain [1]. Additionally, the use of chloramines can also require the installation of additional equipment, such as dechloramination systems, to remove the chloramines from the water before it is distributed to consumers [2].

Another significant cost associated with using chloramines is the cost of chemicals. Chloramines are typically made by adding ammonia to chlorine, which can be costly to purchase and transport [3]. Additionally, the use of chloramines can also require the use of additional chemicals, such as corrosion inhibitors, to protect the distribution system [4].

Labor costs can also be a significant factor in the use of chloramines. The use of chloramines requires specialized training and knowledge, which can increase labor costs. [5] Additionally, regular monitoring and testing of the chloramines in the water, as well as the maintenance of equipment and chemicals, can also add to labor costs.

Controlling DBP formation can also come with significant economic costs. This can include the cost of additional equipment and chemicals, as well as the cost of labor to implement and maintain control measures. [6] Additionally, the cost of fines and penalties for non-compliance with DBP regulations can also be a significant economic cost.

In conclusion, the use of chloramines as a disinfectant in water treatment systems can come with significant economic costs. These costs include the costs of equipment, chemicals, and labor, as well as the costs associated with controlling DBP formation. Water treatment facilities must carefully consider these costs when choosing a disinfection method and implementing control measures to ensure compliance with regulations and protect public health.

[1] J. C. Crittenden and G. M. Crittenden, "Chloramine feed systems," Journal of the American Water Works Association, vol. 81, no. 8, pp. 71-77, 1989.
[2] A. M. Saad and A. A. Al-Mamun, "Dechlorination of chloraminated drinking water: A review," Journal of Environmental Management, vol. 92, no. 1, pp. 1-10, 2011.
[3] W. T. Reynolds, "The economics of chloramines," Journal of the American Water Works Association, vol. 91, no. 6, pp. 77-82, 1999.
[4] R. G. Brown, "Corrosion inhibitors for drinking water distribution systems," Journal of the American Water Works Association, vol. 95, no. 2, pp. 95-104, 2003.
[5] J. W. Edwards and J. L. Farrah, "Chloramines in drinking water," Journal of the American Water Works Association, vol. 94, no. 12, pp. 92-98, 2002.
[6] J. M. Symons, "Control of disinfection by-products in drinking water," Journal of the American Water Works Association, vol. 94, no. 12, pp. 99-107, 2002.

The regulatory framework for chloramines and DBPs

water testing regulations

The use of chloraminesand the control of disinfection by-products (DBPs) are regulated by various laws and regulations. This subtopic will examine the regulatory framework for chloramines and DBPs, including the standards set by the Environmental Protection Agency (EPA) and other organizations.

The EPA sets national drinking water standards for DBPs through the Safe Drinking Water Act. These standards include maximum contaminant levels (MCLs) for various DBPs, including trihalomethanes (THMs) and haloacetic acids (HAAs), which are known to be formed when chloramines are used as a disinfectant. [1] Water treatment facilities are required to comply with these standards and must regularly monitor and report the levels of DBPs in their water to the EPA.

In addition to the EPA, states and municipalities also have the authority to set their own regulations for the use of chloramines and the control of DBPs. These regulations may be more stringent than the national standards set by the EPA. [2] For example, some states have set lower MCLs for certain DBPs or have implemented additional control measures to reduce the formation of DBPs.

Other organizations, such as the American Water Works Association (AWWA) and the Water Research Foundation (WRF), also play a role in setting guidelines and recommendations for the use of chloramines and the control of DBPs. These organizations provide guidance and best practices for water treatment facilities to follow in order to effectively control the formation of DBPs and ensure the safety of treated water [3].

In conclusion, the use of chloramines and the control of DBPs are regulated by various laws and regulations set by the EPA and other organizations. The EPA sets national drinking water standards for DBPs through the Safe Drinking Water Act, while states and municipalities also have the authority to set their own regulations. Additionally, organizations such as the AWWA and WRF provide guidelines and best practices for water treatment facilities to follow in order to effectively control the formation of DBPs and ensure the safety of treated water. It is important for water treatment facilities to stay informed and comply with all relevant regulations in order to protect public health and avoid penalties.

[1] Environmental Protection Agency. (2020). Disinfection Byproducts.
[2] American Water Works Association. (2018). Chloramines: An Overview.
[3] Water Research Foundation. (2019). Chloramines in Drinking Water: Current Practice and Research Needs.

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