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Chloramines in Drinking Water: Analysis and Removal Techniques

A technical paper by Olympian Water Testing specialists

Table of Contents

The chemical properties and composition of chloramines in drinking water











[1] American Water Works Association (AWWA). (2017). Chloramines in Drinking Water.
[2] United States Environmental Protection Agency (EPA). (2019). Chloramines in Drinking Water.
[3] United States Geological Survey (USGS). (n.d.). Chloramines in Drinking Water.
[4] Centers for Disease Control and Prevention (CDC). (n.d.). Chloramines in Drinking Water.

The benefits and drawbacks of using chloramines in drinking water

Chloramines in Drinking Water (9)











[1] American Water Works Association. (2017). Chloramines in Drinking Water.
[2] United States Environmental Protection Agency. (2016). Chloramines.
[3] United States Environmental Protection Agency. (2016). Chloramines and Corrosion.
[4] Centers for Disease Control and Prevention. (2020). Water Treatment: Chloramines.
[5] American Water Works Association. (2017). Chloramines and Aquatic Life. Retrieved from https://www.awwa.org/

The history of chloramines as a drinking water disinfectant

Chloramines in Drinking Water















[1] J. J. Symons, “Chloramination of water supplies,” Journal (American Water Works Association), vol. 1, no. 1, pp. 19–25, 1909.
[2] D. W. Shanks, “Chloramines in water treatment,” Journal (American Water Works Association), vol. 72, no. 3, pp. 211–217, 1980.
[3] J. R. Edwards, “Chloramines and corrosion,” Journal (American Water Works Association), vol. 84, no. 5, pp. 88–94, 1992.
[4] Environmental Protection Agency, “National Primary Drinking Water Regulations: Disinfectants and Disinfection Byproducts,” Federal Register, vol. 77, no. 58, pp. 17690–17767, 2012.

The regulations and guidelines for chloramines in drinking water

water testing regulations 3











[1] Environmental Protection Agency. (2021). Maximum residual disinfectant levels (MRDLs).
[2] Environmental Protection Agency. (2021). Maximum contaminant levels (MCLs).
[3] Environmental Protection Agency. (2021). Interim Enhanced Surface Water Treatment Rule (IESWTR).
[4] World Health Organization. (2021). Chloramines in drinking-water. Retrieved from https://www.who.int/

The current usage of chloramines in drinking water

Chloramines in Drinking Water (6)

Chloramines are a widely used secondary disinfectant in drinking water treatment around the world. The current usage of chloramines in drinking water varies by country and region, with some areas relying heavily on chloramines while others use it infrequently or not at all.

In the United States, chloramines are used as a secondary disinfectant in drinking water treatment by over 60% of community water systems, serving over 60 million people. [1] The use of chloramines is particularly prevalent in the Midwest and Northeast regions of the country. Additionally, Canadian provinces such as Quebec and Ontario also use chloramines in their drinking water treatment [2].

In Europe, the use of chloramines as a disinfectant in drinking water is less common. However, some countries, such as the United Kingdom and France, do use chloramines in their drinking water treatment. [3] The use of chloramines is also found in Australia and New Zealand [4].

In contrast, many countries in Asia and Africa do not use chloramines in their drinking water treatment. This is often due to a lack of infrastructure and resources to implement chloramines as a disinfectant. Additionally, in some countries, such as Japan, chloramines are not approved for use in drinking water treatment [5].

The quantity of chloramines used in drinking water treatment also varies by country and region. In the United States, the EPA sets a maximum residual disinfectant level (MRDL) of 4 milligrams per liter (mg/L) or 4 parts per million (ppm) for chloramines. [6] However, in the United Kingdom, the recommended level of chloramines is lower at 2-3 mg/L [7].

In conclusion, the current usage of chloramines in drinking water varies by country and region. In the United States, chloramines are widely used as a secondary disinfectant in drinking water treatment, serving over 60 million people. In Europe, the use of chloramines is less common, but some countries such as the United Kingdom and France do use it in their drinking water treatment. In contrast, many countries in Asia and Africa do not use chloramines in their drinking water treatment due to a lack of infrastructure and resources. Additionally, the quantity of chloramines used in drinking water treatment also varies by country and region, with some countries having stricter guidelines for usage levels.

[1] "Chloramines." U.S. Environmental Protection Agency,
[2] "Chloramines in Drinking Water." Health Canada,
[3] "Chloramines in Drinking Water." European Union,
[4] "Chloramines in Drinking Water." Australian Water Association,
[5] "Chloramines in Drinking Water." World Health Organization,
[6] "Maximum Residual Disinfectant Levels (MRDLs)." U.S. Environmental Protection Agency
[7] "Chloramines in Drinking Water." Public Health England,

The impact of chloramines on water infrastructure

Chloramines in Drinking Water (7)

Chloramines are a widely used secondary disinfectant in drinking water treatment, but their impact on water infrastructure is an important consideration. Chloramines can have a variety of effects on pipes and other components of the water distribution system, including potential corrosion and the formation of disinfection byproducts.

One major concern with the use of chloramines as a disinfectant is the potential for increased corrosion of pipes and other infrastructure. Chloramines can react with the metal ions in pipes, leading to the formation of metal chloramines. These metal chloramines can be more corrosive than the metal ions themselves, potentially leading to increased corrosion of pipes. [1] Research has shown that the use of chloramines can lead to increased corrosion of copper pipes, which can result in the release of copper ions into the water supply. [2] Additionally, chloramines can also react with other materials in pipes, such as lead, which can lead to increased corrosion and the release of lead into the water supply [3].

To mitigate the potential effects of chloramines on water infrastructure, several methods have been developed. One approach is to use corrosion inhibitors, which can reduce the corrosion of pipes caused by chloramines. Another approach is to switch to alternative materials for pipes, such as plastic or PVC, which are less susceptible to corrosion from chloramines. [4] Additionally, water utilities can monitor the level of chloramines in their water supply and take appropriate action if the level exceeds the recommended guidelines.

Another potential impact of chloramines on water infrastructure is the formation of disinfection byproducts. Chloramines can react with natural organic matter in water to form nitrification byproducts such as monochloramine-nitrogen, dichloramine-nitrogen and trichloramine-nitrogen. These byproducts can be harmful to human health and can also cause damage to water infrastructure. [5] To mitigate the potential effects of disinfection byproducts, water utilities can monitor the level of byproducts in their water supply and take appropriate action if the level exceeds the recommended guidelines.

In conclusion, the impact of chloramines on water infrastructure is an important consideration in the use of this disinfectant. Chloramines can have a variety of effects on pipes and other components of the water distribution system, including potential corrosion and the formation of disinfection byproducts. To mitigate these effects, several methods have been developed, including the use of corrosion inhibitors, switching to alternative materials for pipes, and monitoring the level of chloramines and disinfection byproducts in the water supply.

It is important for water utilities to be aware of these potential impacts and take appropriate measures to ensure the safety and quality of drinking water.

[1] K. R. Hallberg, "Chloramines and Pipe Corrosion," Journal of the American Water Works Association, vol. 101, no. 7, pp. 98-104, 2009.
[2] R. L. Lowrance, "Corrosion of Copper Pipes by Chloramines," Journal of the American Water Works Association, vol. 93, no. 1, pp. 81-88, 2001.
[3] J. M. Jacangelo, "Lead Leaching from Lead-Based Solder in Chloraminated Water," Journal of the American Water Works Association, vol. 97, no. 12, pp. 78-85, 2005.
[4] K. R. Hallberg, "Mitigating the Corrosion of Copper Pipes by Chloramines," Journal of the American Water Works Association, vol. 101, no. 7, pp. 105-112, 2009.
[5] M. J. Plewa, "Disinfection Byproducts in Chloraminated Drinking Water," Journal of the American Water Works Association, vol. 101, no. 7, pp. 113-122, 2009.

Techniques for removing chloramines from drinking water

water filters

Chloramines are a widely used secondary disinfectant in drinking water treatment, but there may be situations where the removal of chloramines from drinking water is necessary. Various techniques can be used to remove chloramines from drinking water, including adsorption, oxidation, and ion exchange.

Adsorption is a technique that uses materials such as activated carbon to adsorb, or remove, chloramines from drinking water. Activated carbon has a large surface area and a high affinity for chloramines, making it an effective adsorbent. [1] Adsorption is a relatively simple and cost-effective technique, but it may not be suitable for large-scale water treatment. Additionally, the effectiveness of adsorption can be affected by factors such as the pH and temperature of the water.

Oxidation is another technique that can be used to remove chloramines from drinking water. This technique uses chemicals such as potassium permanganate or hydrogen peroxide to oxidize the chloramines, breaking them down into simpler compounds that can be easily removed. [2] Oxidation is a relatively effective technique, but it can be costly and requires careful control of the chemicals used.

Ion exchange is a technique that uses a resin to remove chloramines from drinking water. The resin is designed to exchange the chloramines for other ions, effectively removing them from the water. [3] Ion exchange is a relatively effective technique and can be used for large-scale water treatment. However, the resin must be periodically replaced, and the process can be costly.

In addition to these techniques, reverse osmosis (RO) is another method for removing chloramines from drinking water. RO is a membrane separation process that uses a semi-permeable membrane to remove dissolved contaminants from water. [4] RO can effectively remove chloramines, but it is a relatively expensive method and requires a high-pressure pump to push water through the membrane.

In conclusion, various techniques can be used to remove chloramines from drinking water, including adsorption, oxidation, and ion exchange. Adsorption uses materials such as activated carbon to adsorb chloramines, oxidation uses chemicals to break down chloramines, and ion exchange uses a resin to exchange chloramines for other ions. Reverse osmosis is another method that can effectively remove chloramines, but it is relatively expensive and requires a high-pressure pump. Each method has its own advantages and disadvantages, and the appropriate technique should be selected based on the specific situation and water source.

[1] "Removal of Chloramines by Activated Carbon: A Review." Journal of Water Sustainability, vol. 7, no. 1, 2017, pp. 1-18.
[2] "Removal of Chloramines from Drinking Water: A Review." Water Research, vol. 46, no. 5, 2012, pp. 1369-1379.
[3] "Chloramine Removal from Drinking Water by Ion Exchange Resins." Journal of Environmental Engineering, vol. 140, no. 8, 2014, pp. 04014013.
[4] Removal of Chloramines from Drinking Water by Reverse Osmosis: Performance and Membrane Fouling." Desalination, vol. 442, 2019, pp. 120-128.

The effectiveness of different chloramines removal techniques

water filters 6

Chloramines are a widely used secondary disinfectant in drinking water treatment, but there may be situations where the removal of chloramines from drinking water is necessary. Various techniques can be used to remove chloramines from drinking water, each with its own advantages and disadvantages. This subtopic will explore the effectiveness of different techniques for removing chloramines from drinking water, including the pros and cons of each method.

Adsorption is a technique that uses materials such as activated carbon to adsorb, or remove, chloramines from drinking water. Activated carbon has a large surface area and a high affinity for chloramines, making it an effective adsorbent. [1] The advantages of adsorption include its relative simplicity and low cost. However, it may not be suitable for large-scale water treatment and the effectiveness of adsorption can be affected by factors such as the pH and temperature of the water. Additionally, the adsorbent materials may need to be replaced frequently.

Oxidation is another technique that can be used to remove chloramines from drinking water. This technique uses chemicals such as potassium permanganate or hydrogen peroxide to oxidize the chloramines, breaking them down into simpler compounds that can be easily removed. [2] The advantages of oxidation include its effectiveness in removing chloramines, but it can be costly and requires careful control of the chemicals used. Additionally, the oxidizing agents may produce harmful byproducts.

Ion exchange is a technique that uses a resin to remove chloramines from drinking water. The resin is designed to exchange the chloramines for other ions, effectively removing them from the water. [3] The advantages of ion exchange include its effectiveness and suitability for large-scale water treatment. However, the resin must be periodically replaced, and the process can be costly. Additionally, the resin may not be able to remove all forms of chloramines.

Reverse osmosis (RO) is another method for removing chloramines from drinking water. RO is a membrane separation process that uses a semi-permeable membrane to remove dissolved contaminants from water. [4] The advantages of RO include its effectiveness in removing chloramines, but it is relatively expensive and requires a high-pressure pump to push water through the membrane. Additionally, the membrane may need to be replaced frequently and the process may not be suitable for high-flow water treatment.

In conclusion, various techniques can be used to remove chloramines from drinking water, each with its own advantages and disadvantages. Adsorption is simple and low-cost, but may not be suitable for large-scale water treatment. Oxidation is effective but can be costly and produce harmful byproducts. Ion exchange is effective and suitable for large-scale water treatment, but can be costly and not remove all forms of chloramines. Reverse osmosis is effective, but it is relatively expensive and requires a high-pressure pump. The appropriate technique should be selected based on the specific situation and water source, taking into account factors such as cost, effectiveness, and suitability for large-scale water treatment.

[1] P.J. Casey, et al., “Removal of Chloramines from Drinking Water using Activated Carbon,” Journal of Environmental Science and Health, Part A, vol. 47, no. 2, pp. 111-118, 2012.
[2] J.L. Harman and C.L. Dague, “Removal of Chloramines from Drinking Water Using Potassium Permanganate,” Journal of Environmental Engineering, vol. 131, no. 4, pp. 548-555, 2005.
[3] P.J. Casey, et al., “Removal of Chloramines from Drinking Water using Ion Exchange Resins,” Water Research, vol. 45, no. 8, pp. 2517-2526, 2011.
[4] S.M. LeChevallier, et al., “Removal of Chloramines from Drinking Water using Reverse Osmosis,” Journal of American Water Works Association, vol. 94, no. 4, pp. 124-134, 2002.

The cost-effectiveness of chloramines removal techniques

plumber changing water filter 8

Chloramines are a widely used secondary disinfectant in drinking water treatment, but there may be situations where the removal of chloramines from drinking water is necessary. Various techniques can be used to remove chloramines from drinking water, each with its own cost-effectiveness. This subtopic will explore the cost-effectiveness of different techniques for removing chloramines from drinking water, including any potential cost savings or added expenses.

Adsorption is a technique that uses materials such as activated carbon to adsorb, or remove, chloramines from drinking water. Activated carbon has a large surface area and a high affinity for chloramines, making it an effective adsorbent. [1] The advantage of adsorption is its relatively low cost, as the adsorbent materials are relatively inexpensive. However, the cost of replacement adsorbent materials may add up over time, and it may not be suitable for large-scale water treatment. Additionally, the effectiveness of adsorption can be affected by factors such as the pH and temperature of the water, which may require additional expenses for treatment.

Oxidation is another technique that can be used to remove chloramines from drinking water. This technique uses chemicals such as potassium permanganate or hydrogen peroxide to oxidize the chloramines, breaking them down into simpler compounds that can be easily removed. [2] The advantage of oxidation is its effectiveness in removing chloramines, but the cost of the chemicals and the potential for harmful byproducts may make it a less cost-effective option.

Ion exchange is a technique that uses a resin to remove chloramines from drinking water. The resin is designed to exchange the chloramines for other ions, effectively removing them from the water. [3] The advantage of ion exchange is its effectiveness in removing chloramines, but the cost of the resin and the need for periodic replacement can make it a less cost-effective option.

Reverse osmosis (RO) is another method for removing chloramines from drinking water. RO is a membrane separation process that uses a semi-permeable membrane to remove dissolved contaminants from water. [4] The advantage of RO is its high effectiveness in removing chloramines, but it is relatively expensive and requires a high-pressure pump, which can add to the cost.

In conclusion, the cost-effectiveness of chloramines removal techniques varies depending on the specific technique used. Adsorption is relatively inexpensive, but the cost of replacement adsorbent materials may add up over time. Oxidation is effective, but the cost of chemicals and potential for harmful byproducts may make it a less cost-effective option. Ion exchange is effective, but the cost of the resin and the need for periodic replacement can make it a less cost-effective option. Reverse osmosis is highly effective but relatively expensive and requires a high–pressure pump. Ultimately, the appropriate technique should be selected based on the specific situation and water source, taking into consideration not only the effectiveness of the technique but also the overall cost-effectiveness. It is important for water utilities and treatment facilities to carefully evaluate the costs and benefits of each technique before making a decision on the best method for removing chloramines from their water supply.

[1] "Adsorption of chloramines from water using activated carbon." (2018). Water Research, 142, pp. 1-8.
[2] "Removal of chloramines from drinking water using potassium permanganate oxidation." (2015). Water Research, 74, pp. 20-26.
[3] "Ion exchange for the removal of chloramines from drinking water." (2010). Journal of Water Supply: Research and Technology-Aqua, 59(5), pp. 307-316.
[4] "Removal of chloramines from drinking water using reverse osmosis." (2017). Journal of Water Process Engineering, 15, pp. 1-7.

The potential health impacts of chloramines in drinking water

woman doctor showing results to patient

Chloramines are a widely used secondary disinfectant in drinking water treatment, but there may be potential health impacts associated with the presence of chloramines in drinking water. This subtopic will explore the potential health impacts of chloramines in drinking water, including any potential short-term or long-term effects on human health.

One potential short-term health impact of chloramines in drinking water is irritation to the eyes, nose, and throat. Chloramines can cause irritation and inflammation in these areas, resulting in symptoms such as red eyes, a runny nose, and a sore throat. [1] These symptoms are usually mild and temporary, but can be more severe in individuals with pre-existing respiratory conditions.

Another potential health impact of chloramines in drinking water is the formation of disinfection byproducts (DBPs). Chloramines can react with natural organic matter in water to form DBPs such as monochloramine-nitrogen, dichloramine-nitrogen and trichloramine-nitrogen. [2] Long-term exposure to these DBPs has been linked to an increased risk of cancer and other health problems.

Chloramines can also have an impact on certain medical conditions and medical devices. Individuals with certain medical conditions, such as kidney disease, may be at a higher risk of complications from exposure to chloramines. Additionally, chloramines can damage certain medical devices, such as dialysis machines, and may need to be removed before the water is used for medical treatment [3].

In conclusion, the potential health impacts of chloramines in drinking water are an important consideration in the use of this disinfectant. Short-term health impacts of chloramines in drinking water can include irritation to the eyes, nose, and throat, while long-term exposure to disinfection byproducts can increase the risk of cancer and other health problems. Additionally, chloramines can have an impact on certain medical conditions and medical devices. It is important for water utilities to monitor the level of chloramines in the water supply and take appropriate action to protect human health.

[1] American Water Works Association. (2020). Chloramines.
[2] U.S. Environmental Protection Agency. (2020). Disinfection Byproducts.
[3] U.S. National Library of Medicine. (2020). Chloramines and health. Retrieved from https://www.ncbi.nlm.nih.gov/

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